Unlike my other rotations, this term my work is mostly based in the lab. My goal is to understand how to best grow crystal films for use in solar cells. Since there is very little known about the exact science underlying the growth process for these crystals, I have to go through a lot of trial and error, iterating through samples until I arrive at something novel. This post will summarize just one of those many iterations.
[peg-image src=”http://lh3.googleusercontent.com/-HVMN-eJOs5k/VYzwhEafo5I/AAAAAAAALsg/TDBHaE_EhWw/s144-o/IMG_20150625_083545.jpg” href=”https://picasaweb.google.com/105819570346662635782/Qi?authkey=Gv1sRgCKKkk5ysjZaawAE#6164566440874582930″ caption=”IMG_20150625_083545.jpg” type=”image” alt=”IMG_20150625_083545.jpg” image_size=”3120×4160″ ]
The first thing to be aware of is that these crystals are very sensitive. Too much exposure to air will cause the crystals to degrade, so to safeguard against that, I have to prepare the samples in a clean room. This requires me to put on a full body suit as shown above. In addition, inside this already filtered clean room, I synthesize these crystals inside a nitrogen filled glove box. By mixing two precursor chemicals and spinning them onto a small piece of glass, I can uniformly spread the solution as the crystals grows.
[peg-image src=”http://lh3.googleusercontent.com/-DII3w798cQs/VYzwhO46__I/AAAAAAAALsg/HTML5wPzmqg/s144-o/IMG_20150625_084053.jpg” href=”https://picasaweb.google.com/105819570346662635782/Qi?authkey=Gv1sRgCKKkk5ysjZaawAE#6164566443686559730″ caption=”IMG_20150625_084053.jpg” type=”image” alt=”IMG_20150625_084053.jpg” image_size=”4160×3120″ ]
The result is shown below, though these were not the best examples, another reason why I have to do this process so many times. Some samples come out so bad that there’s no point using them further, but for those that are decent, I move on to measuring their characteristics.
[peg-image src=”http://lh3.googleusercontent.com/-IsOX935-Tg8/VYzwhIMTesI/AAAAAAAALsg/3s3JAMLKi_U/s144-o/IMG_20150625_093931.jpg” href=”https://picasaweb.google.com/105819570346662635782/Qi?authkey=Gv1sRgCKKkk5ysjZaawAE#6164566441888807618″ caption=”IMG_20150625_093931.jpg” type=”image” alt=”IMG_20150625_093931.jpg” image_size=”4160×3120″ ]
The first step is to determine how well ordered of a crystal we have. This is most easily measured by looking at X-ray diffraction. A beam of X-rays is fired at an angle to the sample, and based on the type of crystal structure, peaks in the reflection will appear based on the amount of that structure type.
[peg-image src=”http://lh3.googleusercontent.com/-ld0j2yqQ3sE/VYzwhF0zpYI/AAAAAAAALsg/Chk3B-a_A_c/s144-o/IMG_20150625_135622.jpg” href=”https://picasaweb.google.com/105819570346662635782/Qi?authkey=Gv1sRgCKKkk5ysjZaawAE#6164566441253381506″ caption=”IMG_20150625_135622.jpg” type=”image” alt=”IMG_20150625_135622.jpg” image_size=”4160×3120″ ] [peg-image src=”http://lh3.googleusercontent.com/-dAj4sKvUwk4/VYzwhH1DrPI/AAAAAAAALsg/VYGSGCb_OzQ/s144-o/IMG_20150625_135634.jpg” href=”https://picasaweb.google.com/105819570346662635782/Qi?authkey=Gv1sRgCKKkk5ysjZaawAE#6164566441791302898″ caption=”IMG_20150625_135634.jpg” type=”image” alt=”IMG_20150625_135634.jpg” image_size=”3120×4160″ ]
Once the samples have been measured for their crystallinity, the next step is to look at the surface in more detail to see how smooth the samples are. Smooth of course is a relative term, but for these studies we would like the roughness to be on the order of nanometers. To do this, we need a very precise instrument known as an Atomic Force Microscope. The main implement is a very time cantilever, which is positioned just above the sample but not in direct contact with it. The electromagnetic repulsion from the surface affects the cantilever’s resonance, which can then be measured as a magnitude. This allows an extremely detailed surface map to be made, so long as the system is protected from external vibrations.
[peg-image src=”http://lh3.googleusercontent.com/-zSkQtc0KL0U/VYzwhDxiX8I/AAAAAAAALsg/LktGrwT9UJc/s144-o/IMG_20150625_151046.jpg” href=”https://picasaweb.google.com/105819570346662635782/Qi?authkey=Gv1sRgCKKkk5ysjZaawAE#6164566440702795714″ caption=”IMG_20150625_151046.jpg” type=”image” alt=”IMG_20150625_151046.jpg” image_size=”3120×4160″ ]
Once the map is made, the mean height of the surface can be used to quantify the roughness of the surface, and with any luck individual crystal grains can also be measured. The largest grains I have ever made were one micron, which may not sound like much, but every small step is something to be celebrated in this line of work.
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